Name | Phenylarsine oxide |
Synonyms | Oxophenylarsine oxo(phenyl)arsane Phenylarsine oxide mixture of oligomers Phenylarsine oxide solution |
CAS | 637-03-6 |
EINECS | 211-275-3 |
InChI | InChI=1/C6H5AsO/c8-7-6-4-2-1-3-5-6/h1-5H |
Molecular Formula | C6H5AsO |
Molar Mass | 168.025 |
Melting Point | 145-148℃ |
Water Solubility | Soluble in dimethyl sulfoxide, chloroform, benzene, ether, ethanol, 50:50 dimethyl sulfoxide:1 M hydrochloric acid (3.0 mg/ml) and toluene. Insoluble in water. |
Appearance | Morphological powder |
Color | white to yellow |
Merck | 14,6949 |
BRN | 2935227 |
Storage Condition | Poison room |
Stability | Stable. |
MDL | MFCD00131620 |
Physical and Chemical Properties | Crystallization of chemical properties. Melting point 144-146 ℃(119-120 ℃). Soluble in chloroform, hot ethanol, hot benzene, slightly soluble in ethanol, insoluble in water and ether. |
Use | Uses for organic synthesis. The product is highly toxic and is used as an insecticide. |
Hazard Symbols | T - Toxic N - Dangerous for the environment |
Risk Codes | R23/25 - Toxic by inhalation and if swallowed. R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. |
Safety Description | S20/21 - When using do not eat, drink or smoke. S28A - After contact with skin, wash immediately with plenty of water. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60 - This material and its container must be disposed of as hazardous waste. S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
UN IDs | UN 3465 6.1/PG 3 |
WGK Germany | 3 |
RTECS | CH8100000 |
TSCA | Yes |
HS Code | 29310099 |
Hazard Class | 6.1 |
Packing Group | III |
Toxicity | LD50 ipr-mus: 1930 mg/kg JPETAB 74,210,42 |
Raw Materials | Potassium iodide Sulfur dioxide PHENYLARSONIC ACID |
Solubility | DMSO: 50 mg/mL |
EPA chemical information | Oxophenylarsine (637-03-6) |
Mix phenylarsenic acid, methanol, and concentrated hydrochloric acid in a weight ratio of 1:5:2, add a little potassium iodide, and then add sulfur dioxide to saturation. Dissolve the oily benzene dichloro arsenic generated by the reaction with sodium hydroxide solution, and then neutralize it with hydrochloric acid to precipitate the benzene arsenic oxygen.